Couple of links (Which I need to have a further read of)
Legacy Url Routing - converting your ASP.net application to a MVC, how to route the old aspx page to redirect to the MVC required view.
Asp.Net Routing Debugger - allows you to type in URLs and it shows which routes match it (nice :) )
three Common ASP.NET MVC URL Routing Issues - as title suggests
(in a nut shell)
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Register the mappings in the correct order
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Set the redirect of the default.aspx
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parameter names match